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FIGURE 7-3

Consider the following four scenarios: 1 A company needing to reach a decision on the placement of a new factory invokes a sophisticated nancial forecasting model from an ASP, providing it with access to appropriate proprietary historical data from a corporate database on storage systems operated by an SSP During the decision-making meeting, what-if scenarios are run collaboratively and interactively, even though the division heads participating in the decision are located in different cities The ASP itself contracts with a cycle provider for additional oomph during particularly demanding scenarios, requiring of course that cycles meet desired security and performance requirements 2 An industrial consortium formed to develop a feasibility study for a next-generation supersonic aircraft undertakes a highly accurate multidisciplinary simulation of the entire aircraft.

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This simulation integrates proprietary software components developed by different participants, with each component operating on that participant s computers and having access to appropriate design databases and other data made available to the consortium by its members 3 A crisis management team responds to a chemical spill by using local weather and soil models to estimate the spread of the spill, determining the impact based on population location as well as geographic features such as rivers and water supplies, creating a short-term mitigation plan (perhaps based on chemical reaction models), and tasking emergency response personnel by planning and coordinating evacuation, notifying hospitals, and so forth 4 Thousands of physicists at hundreds of laboratories and universities worldwide come together to design, create, operate, and analyze the products of a major detector at CERN, the European high energy physics laboratory.

The code in Listing 28.1 is available in the Web site files as HelloService.cfc in the ColdFusion files of the chapter28 project. n

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During the analysis phase, they pool their computing, storage, and networking resources to create a Data Grid capable of analyzing petabytes of data [8 10] These four examples differ in many respects: the number and type of participants, the types of activities, the duration and scale of the interaction, and the resources being shared But they also have much in common, as discussed in the following (see also Figure 61) In each case, a number of mutually distrustful participants with varying degrees of prior relationship (perhaps none at all) want to share resources in order to perform some task Furthermore, sharing is about more than simply document exchange (as in virtual enterprises [11]): it can involve direct access to remote software, computers, data, sensors, and other resources For example, members of a consortium may provide access to specialized software and data and/or pool their computational resources.

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Resource sharing is conditional: each resource owner makes resources available, subject to constraints on when, where, and what can be done For example, a participant in VO P of Figure 61 might allow VO partners to invoke their simulation service only for simple problems Resource consumers may also place constraints on properties of the resources they are prepared to work with For example, a participant in VO Q might accept only pooled computational resources certi ed as secure The implementation of.

Asymmetric Hydrogenation. Asymmetric hydrogenation with good enantioselectivity of unfunctionalized prochiral alkenes is difficult to achieve. I44 ,145 Chiral rhodium complexes, which are excellent catalysts in the hydrogenation of activated multiple bonds (first, in the synthesis of ex-amino acids by the reduction of ex-Nacylamino-ex-acrylic acids), give products only with low optical yields. 144, 146-149 The best results (",60% ee) were achieved in the reduction of ex-ethyl styrene by a rhodium catalyst with a diphosphinite ligand. 150 Metallocene complexes of titanium, lSI-ISS zirconium,155-157 and lanthanides 158 were used in recent studies to reduce the disubstituted C-C double bond with medium enantioselectivity.

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